Mg‐Based System for H 2 Sorption from CH 4 /H 2 Gas Mixture

H.1 H.2 H.3 H.4

PREPARATION AND CHARACTERIZATION OF [Ni (MAP) ] ; H- MAP = 2- (METHYLAMINO) PYRIDINE H. Aghabozorg* and H. H. Monfared

We have recently synthesized [Ni (MAP) ] complex [H-MAP= 2- (methylamino) pyridine]. 2- (Methy1amino)pyridine reacts with MeLi in THF and generates the lithium salt (Li-MAP). Further reaction of NiCl with two equivalent of this ligand in THF leads to the formation of a dark red solution. Analytical data, molecular weight, and magnetic susceptibility of this complex confirm the formula [N...

Gas-phase synthesis of the benzyl radical (C(6)H(5)CH(2)).

Dicarbon (C2 ), the simplest bare carbon molecule, is ubiquitous in the interstellar medium and in combustion flames. A gas-phase synthesis is presented of the benzyl radical (C6 H5 CH2 ) by the crossed molecular beam reaction of dicarbon, C2 (X(1) Σg (+) , a(3) Πu ), with 2-methyl-1,3-butadiene (isoprene; C5 H8 ; X(1) A') accessing the triplet and singlet C7 H8 potential energy surfaces (PESs)...

Infrared Dual - Gas CH 4 / C 2 H 6 Sensor Using Two Continuous - Wave Interband Cascade Lasers

 Abstract—An infrared dual-gas sensor system for the simultaneous detection and monitoring of methane (CH4) and ethane (C2H6) at parts-per-billion by volume (ppbv) concentration levels was developed using two room temperature, distributed feedback (DFB) interband cascade lasers (ICLs) and two miniature multipass cells with an effective absorption length of 54.6 m. Laser direct absorption spect...

Ion Chemistry in Cold Plasmas of H 2 with Ch

The distributions of ions and neutrals in low pressure (≈ 10 mbar) DC discharges of pure hydrogen and of hydrogen with small admixtures (5%) of CH4 and N2 have been determined by mass spectrometry. Besides the mentioned plasma precursors, appreciable amounts of NH3 and C2Hx hydrocarbons, probably mostly from wall reactions, are detected in the gas phase. Primary ions, formed by electron impact ...